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The ATFL sustains damage in approximately 85% of ankle sprains

doi: 10.1016/j.tins.2020.09.011 250 QuadtLCritchleyHDGarfinkelSN

Therefore, path 1 involving two successive [2,3]-sigmatropic rearrangements is mainly responsible for the two para -selective amination reactions (for details see Supplementary Figs 211 and Supplementary Data 1)

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