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Even if we are perfect about eating well, hydrating enough, and keeping healthy habits up (and who is?), our skin barrier is constantly bombarded by external attacks

No, it is the acetylated form of cysteine and acts as a precursor to cysteine and glutathione
The 'PPAR signaling pathway' and 'phospholipase D signaling pathway', by regulating fatty acid degradation and glycerophospholipid metabolism, integrate metabolic flux with cellular functional responses to maintain energy homeostasis (42)

Vasopressin, for instance, is an anti-diuretic peptide

From the onset of biological development, intracellular reactive oxygen species (ROS) homeostasis is self-regulated to ensure the maintenance of ROS levels and a dynamic equilibrium within cells and tissues [2, 3]
ROS and RNS are endogenously produced by inflammatory cells, during cellular respiration, and by enzymes, but are carefully controlled by antioxidant systems