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Once you break the seal on any water for injection, its open to contamination

-18C and below - 3 years

[DOI] [PubMed] [Google Scholar] 268.Baric M., Sever A.Z., Vuletic L.B., Rasic Z., Sever M., Drmic D., Pavelic-Turudic T., Sucic M., Vrcic H., Seiwerth S., et al

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Malik, In Vitro and in Vivo Studies of pH-Sensitive GHK-Cu-Incorporated Polyaspartic and Polyacrylic Acid Superabsorbent Polymer, American Chemical Society (ACS), Nov
Eligible studies included healthy, normal to overweight adults over 17 years of age who engaged in exercise and daily collagen peptide (CP) supplementation for a minimum of 8 weeks (except one 3-week trial only included for maximal strength)
