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3, 4, 5 It is noteworthy that increased vascular oxidative stress is thought to be involved in the pathogenesis of both EH 6 and CS

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At 3.5 mM cysteine, ~9% of the overall sample composition comprised [4Fe4S] 2+ clusters (grey dashed line) 43,44,47 , with an isomer shift of 0.35 mm/s and E q of 1.01 mm/s, while the remaining 26.3% was attributed to ferrous iron with an expanded (either 5 or 6) coordination 44,48 (orange dashed line, of 1.02 mm/s and E q of 2.97 mm/s)

However, when the balance between pro-oxidants and antioxidants is adversely perturbed, redox stress, including oxidative stress and reductive stress, occurs (Fig