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Nat Rev Immunol 2009;9:16274
ICD-11, International classification of diseases most recent iteration
the Fate of Foreign Compounds in Biological Systems, 48 (4), 325331
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In this final step, glutamine synthetase first reacts with gamma-glutamyl-cysteine to form an electrophilic acylphosphate intermediate by transfer of the gamma-phosphate of ATP to gamma-glutamylcysteine, and then the amino group of glycine acts as a nucleophile to attack the acylphosphate intermediate to form glutathione (28
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