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Guanylate (5-guanylate monophosphate [GMP], a 5-ribonucleotide) was also found to have umami 15 , and this substance was later found to exist abundantly in mushrooms

doi: 10.1104/pp.106.094409

Also, Jamilian et al

8 Glutathione is a small, odorant, polar molecule of only 307.33 Da, suggesting that the molecule may be well absorbed without enhancers, but pharmacokinetic studies of intranasally administered glutathione have not been conducted in either healthy or diseased populations (Table 1)

(2) antioxidative defense