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Beyond direct H 2 O 2 scavenging, GSH also detoxifies lipid peroxidation byproducts, including malondialdehyde (MDA) and 4-HNE, through GST-mediated conjugation, facilitating their removal and preventing secondary cytotoxic signaling 91,92

The released Mn 2+ can in turn mediate Fenton-like reactions by catalyzing the generation of highly active OH from H 2 O 2 (32) to induce high oxidative stress in tumor cells and the production of proinflammatory factors, such as TNF- (5255)

Cabungcal JH, Counotte DS, Lewis E, Tajeda HA, Piantadosi P, Pollock C, et al

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[DOI] [Google Scholar] 217.Quelca Tancara B., Solares Espinoza M., Cortez J., Velez G., Salcedo Y., Salinas A.M., Carvajal R

573 Alternatively, GRP132 activation by 9-HODE, but not 13-HODE, stimulates pro-inflammatory cytokine production, and cell cycle arrest in normal human epidermal keratinocytes, 562 but not GRP132-dependent activities in macrophages