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The 5-carbon skeleton of its structure allows the keto-enol tautomers and transient, joint-electron activation states at the 2,3- and 4,5-bounds in positions of enzymatic catalysis

Algal Res 23:96103

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These findings are consistent with those for other antioxidant enzymes: for example, lack of peroxiredoxin 3, a mitochondrially localized antioxidant enzyme, also augments apoptotic signaling in some cell types (60)

Lee, M., Ghosh, U., Thurber, K

Located within the mitochondrial matrix, the TCA cycle produces the reduced cofactors NADH and FADH_2, which serve as the primary electron donors for the electron transport chain (ETC)