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The doublet with high quadrupole splitting (pink line) is indicative of valence localised Fe 2+ centres, most probably with quasi-tetrahedral sulfur coordination, i.e

Food Chem Toxicol 2005

Manipulation of Ascorbate Biosynthetic, Recycling, and Regulatory Pathways for Improved Abiotic Stress Tolerance in Plants
[PubMed] [Google Scholar] 44.Ma P.C., Jagadeeswaran R., Jagadeesh S., Tretiakova M.S., Nallasura V., Fox E.A., Hansen M., Schaefer E., Naoki K., Lader A., et al

Salinity, primarily resulting from NaCl, is a significant abiotic stressor affecting both irrigated and non-irrigated lands

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