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Regarding exogenous glutathione intake, scientific studies indicate that this is distinct from endogenous synthesis and may not substitute or replicate the protective metabolic roles fully

Discussion The extensive global use of ATZ ensures continued human and wildlife exposure to this herbicide and its metabolites, raising significant public and environmental health concerns

BMC Plant Biol 10:249 Chang CC, lesak I, Jord L, Sotnikov A, Melzer M, Miszalski Z, Mullineaux PM, Parker JE, Karpiska B, Karpiski S (2009) Arabidopsis chloroplastic glutathione peroxidases play a role in cross talk between photooxidative stress and immune responses