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M.et al (2010)

This can happen due to taking the wrong dosage of dietary supplements, but also because SAM cannot be utilised due to genetic mutations, for instance

Urban air pollutants, including particulate matter (PM), ozone (O), and nitrogen dioxide (NO), have been shown to penetrate the stratum corneum and directly induce OS by activating toll-like receptors (TLRs) and the aryl hydrocarbon receptor (AhR) pathway [22]

10.1111/j.1538-7836.2004.01085.x J Thromb Haemost

Pair with curcumin or omega-3s to further reduce inflammation

So basically, when this balance cannot be obtained in excess of eumelanin, then one would appear a lot darker along with hyperpigment