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Weickert CS, Fung SJ, Catts VS, Schofield PR, Allen KM, Moore LT, et al

The results of the above animal experimental studies proved the positive effect of vitamin E, which prompted more researchers to seek its effectiveness in clinical trials
So I wouldnt say that its necessarily better to get the vitamin D from the sun than from a vitamin D supplement or from eating fish or from eating cod liver oil

doi: 10.1046/j.1365-2826.1997.00605.x

Reactive oxygen species (ROS), produced via GSH-mediated pathways, can serve as danger-associated molecular patterns, stimulating dendritic cells and promoting T-cell expansion [82]

This has been demonstrated to inhibit the proliferation and metastasis of thyroid cancer and to enhance the innate immune response [143]
