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This results in a substantial buildup of hydrogen peroxide in the cytosol, which works to reversibly oxidize catalytic cysteine residues in phosphatases, ultimately preventing them from dephosphorylating key downstream TCR signaling proteins, including ZAP-70, PTEN, and LAT ( Figure 1 ) ( ROS also play a critical role in delineating T cell subset formation and, reciprocally, cytokines, the messengers of the immune system, greatly influence ROS

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Moujalled D, Grubman A, Acevedo K et al (2017) TDP-43 mutations causing amyotrophic lateral sclerosis are associated with altered expression of RNA-binding protein hnRNP K and affect the Nrf2 antioxidant pathway

Further research indicated that ShtIX induces ferroptosis in NSCLC cells by blocking the Nrf2/HO-1 signalling pathway [92]

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102 The first step of lipid peroxidation is the abstraction of a bis -allylic hydrogen, generating a stabilized pentadienyl radical