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Its accumulation reflects impaired glutathione regeneration, loss of regulatory control within the -glutamyl cycle, and metabolic conditions that favour diversion of intermediates away from productive glutathione synthesis

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This residual risk is likely attributable at least in part to inflammation

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Lipoic acid was detected by LC-MS/MS, with the targeted parent and daughter ions specific to the 12 C or 13 C form of the metabolite

Nat Med 2021 Jan;27(1):165-173 55