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Peak at f =2970-2781 cm -1 pointed out available C-H single bond stretch, at f =1677 cm -1 shows the presence of Aryl C=N double bond stretch, and at f =1691 cm -1 specifies the existence of Aryl C=C double bond stretch, f =717-904 cm -1 indicates the presence of C-H single bond stretch of mono substituted pyridine ring

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While such threatening characters have appeared in childrens media for centuries, fears around stranger-danger began to rise in the 1970s, with the grizzly details of child murders and exploitation making the press with increased fever as the twentieth century progressed (Crane, 2018)